Photolysis of aryl azides to give nitrenes, and their subsequent rearrangement in the presence of water to give 3H-azepinones, is performed in continuous flow in a photoreactor constructed of ...

THE salts of hydrazoic acid are of military interest owing to the fact that many of them are explosive. They range in sensitivity from sodium azide, which is stable, to the heavy metal azides, such as ...

NITRENES, molecular fragments with an electron sextet on nitrogen, are known to be the primary products of the decomposition of organic azides 1–3. Their existence as separate intermediates and their ...

Azides are chemical compounds widely used in synthetic organic chemistry, pharmaceutical sciences, and materials chemistry. However, conventional synthesis methods for azide compounds have severe ...